For me it's probably "Who's Crying Now" by Journey. Neal Schon just crushes it.
Brian May - I Want It All (single)
Ace Frehley - Rock Bottom, Kiss Alive 1
Testament - Return to Serenity
Ace Frehley-Shock Me,Alive 2
Prince at 3:27
I'm more of a breakdown man myself.
Maybe not the greatest but Skid Row's "18 and Life."
Since i been lovin you- Led Zeppelin
Awaken the Dreamers - All Shall Perish
Vela, We Await the Storm - The Human Abstract
Love the one Prince pulled off during that big group of guys playing While my guitar gently weeps.
HeHitsMeBecauseHeLovesMe - I'm more of a breakdown man myself.Doyle - Helena
Hendrix - Pali Gap. Doesnt really qualify as a solo since it's all guitar, bass and drums, but it's pure magic.
Every single solo by Mark Knopfler and EVH. Not my favorite guitarists but my favorite soloists for sure!!!
The guitar MK did on once upon a time in the west is epic. All of the guitar work on Communique is killer!
Dire Straights- Sultans of Swing Alchemy Live
Shine on you crazy diamond
Stairway to Heaven live off The Song Remains the Same album.
Joe Satriani, in that one song. Lol
The second solo in comfortably numb